Where can I find all the CSS parameters and their actual values?
All in alphabetical order at: CSS Property Index which also gives you access to sorting by category.
Clicking on each property redirects you to a page detailing the property: What is it; Valid values; Examples of using
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There is a (yet incomplete) list of CSS properties, selectors and other CSS components at https://developer.mozilla.org/en/CSS_Reference and a whole group of resources http://www.w3.org/Style/CSS/learning
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This is not a very good approach to learning CSS. There are many attributes, but you want to focus on those that work consistently across browsers. And many of the most important properties (display, position) have behavior that depends on the values of other properties, so training them one by one will not allow you to fully understand them.
I recommend the book HTML and CSS Design Patterns as a way to learn the most important attributes and how they interact. It does a great job of targeting behaviors that you can rely on across browsers, as well as catching unexpected dependencies between attributes.
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The mastery of CSS by Andy Budd, Simon Collison, and Cameron Moll is extremely useful as an introduction to the chaotic world of CSS.
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Getting a good book is by far a better way than looking at the specs on the W3C.
I also recommend CSS Mastery and Bulletproof Web Design by Dan Sederholm - great starting points.
For online resources, you should take a look at Sitepoint CSS Link . It's also a great HTML and Javascript resource. You should also browse the articles on A List Apart and 24ways .
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